Institute of Physics of Materials AS CR, v. v. i. > Projects > Microstructure and functional properties refinement by dopant distribution in transparent ceramics - combined experimental and theoretical approach

Microstructure and functional properties refinement by dopant distribution in transparent ceramics - combined experimental and theoretical approach

InvestigatorRNDr. Jiří Svoboda, CSc., DSc.
Number of Project20-14237S
Internal Project Number320410
AgencyGrantová agentura České republiky
Duration2020-01-01 - 2022-12-31

Anotace
Properties of ceramic materials may be enhanced or some new functionalities may be provoked by adding a dopant. The proper function of the dopant is conditioned by its homogeneous distribution in the system. The project aims to describe the dopant distribution by diffusion in the lattice and/or via grain boundaries using the combined theoretical and experimental approaches resulting in optimal processing of (co)doped ceramic materials. Both approaches will be applied to transparent ceramics with photoluminescent properties. The dopant behaviour and consequently system properties depend on lattice structure of the matrix, its chemical composition and on microstructural characteristics and thermodynamic properties of the system; especially the solubility of dopants in the matrix is essential. Several dopant/matrix combinations will be investigated to cover all classes of possible interactions between the dopant and the matrix. Based on the acquired knowledge, the qualified recommendations for preparing of doped ceramic materials of excellent properties will be formulated.


2022

Svoboda J., Drdlíková K., Drdlík D., Kroupa A., Michalička J., Maca K.: Doping of alumina ceramics by manganese Thermodynamical and experimental approach. Process. Appl. Ceram. 16 (2022) 13-21

Leitner S., Ecker W., Fischer F., Svoboda J.: Thermodynamic trapping and diffusion model for multiple species in systems with multiple sorts of traps. Acta Mater. 233 (2022) 117940

Drdlíková K., Klement R., Svoboda J., Drdlík D., Galusek D., Maca K.: Luminescent Dy3+ and Dy3+/Cr3+ doped transparent Al2O3 ceramics: Microstructure and optical properties. J. Eur. Ceram. Soc. 42 (2022) 4343-4352